NEET Chemistry Coordination Compounds MCQs

    Prepare for NEET Chemistry Coordination Compounds with MCQs & PYQs on NEET.GUIDE. Practice free previous year questions and get expert help to decode structures and isomerism.

    NEET Questions / Chemistry / Coordination Compounds

    51.

    Which one of the following is wrongly matched?

    A

    [Cu(NH3)4]2+                        Square  planar{\left[ {{\rm{Cu}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}} \right]^{2 + }}{\rm{\;\;\;\;\;\;}} - {\rm{\;\;\;\;\;\;Square}}\,{\rm{\;planar}}

    B

    [Ni(CO)4]                                        Neutral  ligand\left[ {{\rm{Ni}}{{\left( {{\rm{CO}}} \right)}_4}} \right]{\rm{\;\;\;\;\;\;\;\;\;\;\;\;\;}} - {\rm{\;\;\;\;\;\;\;Neutral\;ligand}}

    C

    [Fe(CN6)]3                              sp3  d2{\left[ {{\rm{Fe}}\left( {{\rm{C}}{{\rm{N}}_6}} \right)} \right]^{3 - }}{\rm{\;\;\;\;\;\;\;\;}} - {\rm{\;\;\;\;\;\;\;}}s{p^3}\;{d^2}

    D

      [Co(en)3](3+)FollowsEANrule\;{[Co{(en)_3}]^{(3 + )}} - {\rm{Follows}}\,\,{\rm{EAN}}\,\,{\rm{rule}}

    Question Tags

    52.

    A complex of cobalt has five ammonia molecules, one nitro group and two chlorine atoms for each cobalt atom. One mole of this compound produces three mole ions in aqueous solution which on treating with excess of AgNO3{\rm{AgN}}{{\rm{O}}_3} give two mole of AgCl{\rm{AgCl}}. The formula of the compound is:

    A

    [Co(NH3)4NO2Cl][(NH3)Cl]\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{N}}{{\rm{O}}_2}{\rm{Cl}}} \right]\left[ {\left( {{\rm{N}}{{\rm{H}}_3}} \right){\rm{Cl}}} \right]

    B

    [Co(NH3)5Cl][ClNO2]\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_5}{\rm{Cl}}} \right]\left[ {{\rm{ClN}}{{\rm{O}}_2}} \right]

    C

    [Co(NH3)5NO2]Cl2\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_5}{\rm{N}}{{\rm{O}}_2}} \right]{\rm{C}}{{\rm{l}}_2}

    D

    [Co(NH3)5][(NO2)2Cl2]\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_5}} \right]\left[ {{{\left( {{\rm{N}}{{\rm{O}}_2}} \right)}_2}{\rm{C}}{{\rm{l}}_2}} \right]

    Question Tags

    53.

    Which complex compound possesses sp3d2s{p^3}{d^2} hybridisation?

    A

    [Fe(NH3)6]3+{\left[ {{\rm{Fe}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_6}} \right]^{3 + }}

    B

    [Fe(CN)6]4{\left[ {{\rm{Fe}}{{\left( {{\rm{CN}}} \right)}_6}} \right]^{4 - }}

    C

    [Fe(CN)6]3{\left[ {{\rm{Fe}}{{\left( {{\rm{CN}}} \right)}_6}} \right]^{3 - }}

    D

    [Fe(Cl)6]3{\left[ {{\rm{Fe}}{{\left( {{\rm{Cl}}} \right)}_6}} \right]^{3 - }}

    Question Tags

    54.

    When EDTA solution is added to Mg2+M{g^{2 + }} ion solution, then which of the following statements is not true?

    A

    EDTA forms a 1:1 complex with Mg^{2+}.

    B

    The Mg-EDTA complex is stable.

    C

    EDTA does not form a complex with Mg^{2+}.

    D

    The formation of the Mg-EDTA complex reduces free Mg^{2+} ion concentration.

    Question Tags

    56.

    Which one of the following shows maximum value of paramagnetic behaviour?

    A

    [Sc(CN)6]3{\left[ {{\rm{Sc}}{{\left( {{\rm{CN}}} \right)}_6}} \right]^{3 - }}

    B

    [Co(CN)6]3{\left[ {{\rm{Co}}{{\left( {{\rm{CN}}} \right)}_6}} \right]^{3 - }}

    C

    [Ni(CN)4]2{\left[ {{\rm{Ni}}{{\left( {{\rm{CN}}} \right)}_4}} \right]^{2 - }}

    D

    [Cr(CN)6]3{\left[ {{\rm{Cr}}{{\left( {{\rm{CN}}} \right)}_6}} \right]^{3 - }}

    Question Tags

    58.

    Which one of the following has an optical isomer? (en ={\rm{ = }} ethylenediamine)

    A

    [Zn(en)(NH3)2]2+{\left[ {{\rm{Zn}}\left( {{\rm{en}}} \right){{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_2}} \right]^{2 + }}

    B

    [Co(en)3]3+{\left[ {{\rm{Co}}{{\left( {{\rm{en}}} \right)}_3}} \right]^{3 + }}

    C

    [CO(H2O)4(en)]3+{\left[ {{\rm{CO}}{{\left( {{{\rm{H}}_2}{\rm{O}}} \right)}_4}\left( {{\rm{en}}} \right)} \right]^{3 + }}

    D

    [Zn(en)2]2+{\left[ {{\rm{Zn}}{{\left( {{\rm{en}}} \right)}_2}} \right]^{2 + }}

    Question Tags

    59.

    Which compound exhibits optical isomerism?

    A

    Pentaamminenitrocobalt (III) iodide

    B

    Diamminedichloroplatinum (II)

    C

    TransTrans -dicyano-bis-(ethylenediamine) chromium (III) chloride

    D

    Tris-(ethylenediamine)cobalt (III) bromide

    Question Tags

    Showing 51 to 60 of 115 entries

    company logo