The complex ion [Fe(H2O)6]2+ is paramagnetic. Which of the following statements correctly explains this observation using Valence Bond Theory?
H2O is a strong field ligand, resulting in d2sp3 hybridization with no unpaired electrons.
H2O is a weak field ligand, resulting in sp3d2 hybridization with four unpaired electrons in the 3d orbitals of Fe2+.
H2O is a strong field ligand, resulting in sp3d2 hybridization with two unpaired electrons in the 3d orbitals of Fe2+.
H2O is a weak field ligand, resulting in dsp2 hybridization with two unpaired electrons in the 3d orbitals of Fe2+.
Related Questions
Which type of bond is formed by the sideways overlap of atomic orbitals?
Sigma bond
Pi bond
Ionic bond
Hydrogen bond
Consider the molecule . According to Valence Bond Theory, which statement best describes the hybridization and bond angles?
hybridization with bond angles of .
hybridization with bond angles of exactly and .
hybridization with bond angles of .
hybridization with bond angles of approximately and due to lone pair repulsion.
Which of the following explains the square planar geometry of complexes like using Valence Bond Theory?
hybridization with as a weak field ligand.
hybridization with as a strong field ligand.
hybridization with as a weak field ligand.
hybridization with as a strong field ligand.
Which of the following statements is true regarding ?
It is diamagnetic and inner orbital complex
It is diamagnetic and outer orbital complex
It is paramagnetic and inner orbital complex
It is paramagnetic and outer orbital complex
Which type of hybridization occurs in methane ()?
proton plays an important role inβ¦bonding.
Electrovalent
Hydrogen
Covalent
Coordinate
The complex ion [Fe(H2O)6]2+ is paramagnetic. Which of the following statements correctly explains this observation using Valence Bond Theory?
H2O is a strong field ligand, resulting in d2sp3 hybridization with no unpaired electrons.
H2O is a weak field ligand, resulting in sp3d2 hybridization with four unpaired electrons in the 3d orbitals of Fe2+.
H2O is a strong field ligand, resulting in sp3d2 hybridization with two unpaired electrons in the 3d orbitals of Fe2+.
H2O is a weak field ligand, resulting in dsp2 hybridization with two unpaired electrons in the 3d orbitals of Fe2+.
If a complex of nickel with a bidentate ligand is square planar and diamagnetic, what is the likely charge on the complex?
+2
0
-2
+4
Which of the following hybridizations is associated with a square planar complex like ? (Atomic number of Ni = 28)
According to VBT, the number of sigma and pi bonds in ethene () are:
4 sigma and 2 pi
5 sigma and 1 pi
6 sigma and 0 pi
1 sigma and 5 pi