1.

    A reaction proceeds via a two-step mechanism. The first step is a fast, reversible equilibrium with a small equilibrium constant. The second step is slow. Which of the following is MOST likely true about the overall reaction rate?

    A

    The overall rate will be determined solely by the rate of the slow step.

    B

    The overall rate will be independent of the concentration of the intermediate.

    C

    The overall rate will be dependent on the concentrations of the reactants in both steps.

    D

    The equilibrium constant of the first step will have no effect on the overall rate.

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    Related Questions

    1.

    Two molecules A and B collide, but no reaction occurs. Which of the following MUST be true?

    A

    The molecules did not collide with the correct orientation.

    B

    The molecules are not reactive under any conditions.

    C

    The collision did not have sufficient energy to overcome the activation energy barrier.

    D

    The temperature of the system is too low for any reaction to occur.

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    2.

    A reaction proceeds via a two-step mechanism. The first step is a fast, reversible equilibrium with a small equilibrium constant. The second step is slow. Which of the following is MOST likely true about the overall reaction rate?

    A

    The overall rate will be determined solely by the rate of the slow step.

    B

    The overall rate will be independent of the concentration of the intermediate.

    C

    The overall rate will be dependent on the concentrations of the reactants in both steps.

    D

    The equilibrium constant of the first step will have no effect on the overall rate.

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    3.

    Which statement is not correct?

    A

    For endothermic reactions, heat of reaction is lesser than energy of activation

    B

    For exothermic reactions, heat of reaction is more than energy of activation

    C

    For exothermic reactions energy of activation is less in forward reaction than in backward reaction

    D

    For endothermic reactions energy of activation is more in forward reaction than in backward reaction

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