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    4.

    For blasting purpose TNT is mixed with:

    A

    NH4Cl{\rm{N}}{{\rm{H}}_4}{\rm{Cl}}

    B

    NH4NO3{\rm{N}}{{\rm{H}}_4}{\rm{N}}{{\rm{O}}_3}

    C

    NH4NO2{\rm{N}}{{\rm{H}}_4}{\rm{N}}{{\rm{O}}_2}

    D

    (NH4)2SO4{\left( {{\rm{N}}{{\rm{H}}_4}} \right)_2}{\rm{S}}{{\rm{O}}_4}

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    5.

    Among the following statement, the correct statement about PH3{\rm{P}}{{\rm{H}}_3} and NH3{\rm{N}}{{\rm{H}}_3} is:

    A

    NH3{\rm{N}}{{\rm{H}}_3} is a better electron donor because the lone pair of electron occupies spherical s-orbital and is less directional

    B

    PH3{\rm{P}}{{\rm{H}}_3} is a better electron donor because the lone pair of electron occupies sp3s{p^3}orbital and is more directional

    C

    NH3{\rm{N}}{{\rm{H}}_3} is a better electron donor because the lone pair of electron occupies sp3s{p^3}orbital and more directional

    D

    PH3{\rm{P}}{{\rm{H}}_3} is a better electron donor because the lone pair of electron occupies spherical s-orbital and is less directional

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    6.

    Holme’s signals can be obtained by using

    A

    CaC2+CaCN2Ca{C_2} + CaC{N_2}

    B

    CaC2+Ca3P2Ca{C_2} + C{a_3}{P_2}

    C

    CaC2+CaCO3Ca{C_2} + CaC{O_3}

    D

    Ca3P2+CaCN2C{a_3}{P_2} + CaC{N_2}

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    8.

    Consider the following carboxylic acids: CH3CH2COOHCH_3CH_2COOH, CH3COOHCH_3COOH, HCOOHHCOOH. Arrange them in decreasing order of acidity.

    A

    CH3CH2COOH>CH3COOH>HCOOHCH_3CH_2COOH > CH_3COOH > HCOOH

    B

    HCOOH>CH3COOH>CH3CH2COOHHCOOH > CH_3COOH > CH_3CH_2COOH

    C

    CH3COOH>HCOOH>CH3CH2COOHCH_3COOH > HCOOH > CH_3CH_2COOH

    D

    CH3CH2COOH>HCOOH>CH3COOHCH_3CH_2COOH > HCOOH > CH_3COOH

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