1.

    Which of the following statements regarding the oxoacids of phosphorus is INCORRECT?

    A

    Orthophosphoric acid (H3PO4H_3PO_4) is a tribasic acid.

    B

    Hypophosphorous acid (H3PO2H_3PO_2) is a tribasic acid.

    C

    Pyrophosphoric acid (H4P2O7H_4P_2O_7) is a tetrabasic acid.

    D

    Phosphorous acid (H3PO3H_3PO_3) is a dibasic acid.

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    2.

    Which is the correct thermal stability order

    A

    H2Se<H2Te<H2PO<H2O<H2S{H_2}Se < {H_2}Te < {H_2}PO < {H_2}O < {H_2}S

    B

    H2S<H2O<H2Se<H2Te<H2PO{H_2}S < {H_2}O < {H_2}Se < {H_2}Te < {H_2}PO

    C

    H2O<H2S<H2Se<H2Te<H2PO{H_2}O < {H_2}S < {H_2}Se < {H_2}Te < {H_2}PO

    D

    H2PO<H2Te<H2Se<H2S<H2O{H_2}PO < {H_2}Te < {H_2}Se < {H_2}S < {H_2}O

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    3.

    The bond angle in PH3{\rm{P}}{{\rm{H}}_3} is:

    A

    Much lesser than NH3{\rm{N}}{{\rm{H}}_3}

    B

    Equal to that in NH3{\rm{N}}{{\rm{H}}_3}

    C

    Much greater than inNH3{\rm{N}}{{\rm{H}}_3}

    D

    Slightly more than in NH3{\rm{N}}{{\rm{H}}_3}

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    6.

    The bond angle in PH3{\rm{P}}{{\rm{H}}_3} is:

    A

    Much lesser than NH3{\rm{N}}{{\rm{H}}_3}

    B

    Equal to that in NH3{\rm{N}}{{\rm{H}}_3}

    C

    Much greater than inNH3{\rm{N}}{{\rm{H}}_3}

    D

    Slightly more than in NH3{\rm{N}}{{\rm{H}}_3}

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    7.

    The basic character of hydrides of V group is

    A

    NH3>PH3>ASH3>SbH3N{H_3} > P{H_3} > AS{H_3} > Sb{H_3}

    B

    SbH3>ASH3>PH3>NH3Sb{H_3} > AS{H_3} > P{H_3} > N{H_3}

    C

    SbH3>PH3>ASH3>NH3Sb{H_3} > P{H_3} > AS{H_3} > N{H_3}

    D

    NH3>SbH3>PH3>ASH3N{H_3} > Sb{H_3} > P{H_3} > AS{H_3}

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