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    2.

    An aqueous solution of CoCl2{\rm{CoC}}{{\rm{l}}_2} on addition of excess of concentrated HCl{\rm{HCl}} turns blue to formation of

    A

    [CoCl4]2{\left[ {{\rm{CoC}}{{\rm{l}}_4}} \right]^{2 - }}

    B

    [Co(H2O)2Cl4]2{\left[ {{\rm{Co}}{{\left( {{{\rm{H}}_2}{\rm{O}}} \right)}_2}{\rm{C}}{{\rm{l}}_4}} \right]^{2 - }}

    C

    [Co(H2O)22Cl4]2{\left[ {{\rm{Co}}{{\left( {{{\rm{H}}_2}{\rm{O}}} \right)}_2}2{\rm{C}}{{\rm{l}}_4}} \right]^{2 - }}

    D

    [Co(H2O)4Cl2]\left[ {{\rm{Co}}{{\left( {{{\rm{H}}_2}{\rm{O}}} \right)}_4}{\rm{C}}{{\rm{l}}_2}} \right]

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    7.

    In a tetrahedral crystal field, the splitting of d-orbitals is such that:

    A

    The eg set is lower in energy and the t2g set is higher in energy.

    B

    The t2g set is lower in energy and the eg set is higher in energy.

    C

    Both eg and t2g sets are degenerate.

    D

    The d orbitals do not split in a tetrahedral field.

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