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    2.

    Which one of the following octahedral complexes will not show geometrical isomerism? (A and B are monodentate ligands)

    A

    [MA4B2]\left[ {M{A_4}{B_2}} \right]

    B

    [MA5B]\left[ {M{A_5}B} \right]

    C

    [MA2B4]\left[ {M{A_2}{B_4}} \right]

    D

    [MA3B3]\left[ {M{A_3}{B_3}} \right]

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    3.

    Which one of the following has largest number of isomers?(R == alkyl group, en == ethylenediamine)

    A

    [Ru(NH3)4Cl2]+{\left[ {{\rm{Ru}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{C}}{{\rm{l}}_2}} \right]^ + }

    B

    [Co(NH3)5Cl]2+{\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_5}{\rm{Cl}}} \right]^{2 + }}

    C

    [Ir(PR3)2H(CO)]2+{\left[ {{\rm{Ir}}{{\left( {{\rm{P}}{{\rm{R}}_3}} \right)}_2}{\rm{H}}\left( {{\rm{CO}}} \right)} \right]^{2 + }}

    D

    [CO(en)2Cl2]+{\left[ {{\rm{CO}}{{\left( {{\rm{en}}} \right)}_2}{\rm{C}}{{\rm{l}}_2}} \right]^ + }

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    4.

    Coordination isomerism is caused by interchange of ligands between the

    A

    Complex cation and complex anion

    B

    Inner sphere and outer sphere

    C

    Low oxidation and higher oxidation states

    D

    ciscis and transtrans structure

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