Related Questions

    4.

    In which of the following pairs both the complex show optical isomerism?

    A

    Cisβˆ’[Cr(C2O4)2Cl2]3βˆ’;  cisβˆ’[Co(NH3)4Cl2]Cis - {\left[ {{\rm{Cr}}{{\left( {{{\rm{C}}_2}{{\rm{O}}_4}} \right)}_2}{\rm{C}}{{\rm{l}}_2}} \right]^{3 - }};\,\,cis - \left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{C}}{{\rm{l}}_2}} \right]

    B

    [PtCl(dien)]Cl,β€…β€Š[NiCl2Br2]2βˆ’\left[ {{\rm{PtCl}}\left( {{\rm{dien}}} \right)} \right]{\rm{Cl}},{\rm{\;}}{\left[ {{\rm{NiC}}{{\rm{l}}_2}{\rm{B}}{{\rm{r}}_2}} \right]^{2 - }}

    C

    [Co(NO3)3(NH3)3],  cisβˆ’[Pt(en)2Cl2]\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{O}}_3}} \right)}_3}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_3}} \right],\,\,cis - \left[ {{\rm{Pt}}{{\left( {{\rm{en}}} \right)}_2}{\rm{C}}{{\rm{l}}_2}} \right]

    D

    [Co(en)3]Cl3,  cisβˆ’[Co(en)2Cl2]Cl\left[ {{\rm{Co}}{{\left( {{\rm{en}}} \right)}_3}} \right]{\rm{C}}{{\rm{l}}_3},\,\,cis - \left[ {{\rm{Co}}{{\left( {{\rm{en}}} \right)}_2}{\rm{C}}{{\rm{l}}_2}} \right]{\rm{Cl}}

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    6.

    The co-ordination complex which shows linkage isomerism is

    A

    [Co(NH3)5NO2]2+{\left[ {Co{{\left( {N{H_3}} \right)}_5}N{O_2}} \right]^{2 + }}

    B

    [Co(NH3)6]3+{\left[ {Co{{\left( {N{H_3}} \right)}_6}} \right]^{3 + }}

    C

    [Co(NH3)5Br]2+{\left[ {Co{{\left( {N{H_3}} \right)}_5}Br} \right]^{2 + }}

    D

    [Cr(H2O)5Cl]2+{\left[ {Cr{{\left( {{H_2}O} \right)}_5}Cl} \right]^{2 + }}

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    10.

    Which one of the following has largest number of isomers?(R == alkyl group, en == ethylenediamine)

    A

    [Ru(NH3)4Cl2]+{\left[ {{\rm{Ru}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{C}}{{\rm{l}}_2}} \right]^ + }

    B

    [Co(NH3)5Cl]2+{\left[ {{\rm{Co}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_5}{\rm{Cl}}} \right]^{2 + }}

    C

    [Ir(PR3)2H(CO)]2+{\left[ {{\rm{Ir}}{{\left( {{\rm{P}}{{\rm{R}}_3}} \right)}_2}{\rm{H}}\left( {{\rm{CO}}} \right)} \right]^{2 + }}

    D

    [CO(en)2Cl2]+{\left[ {{\rm{CO}}{{\left( {{\rm{en}}} \right)}_2}{\rm{C}}{{\rm{l}}_2}} \right]^ + }

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