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    2.

    In Cr(NH3)4Cl2]Cl{\rm{Cr}}{\left( {{\rm{N}}{{\rm{H}}_3}} \right)_4}{\rm{C}}{{\rm{l}}_2}]{\rm{Cl}} the ligands are:

    A

    NH3{\rm{N}}{{\rm{H}}_3} only

    B

    Clβˆ’{\rm{C}}{{\rm{l}}^ - } only

    C

    Both NH3β€…β€Šandβ€…β€ŠClβˆ’{\rm{N}}{{\rm{H}}_3}{\rm{\;and\;C}}{{\rm{l}}^ - }

    D

    Cr,β€…β€ŠNH3,β€…β€ŠClβˆ’{\rm{Cr}},{\rm{\;N}}{{\rm{H}}_3},{\rm{\;C}}{{\rm{l}}^ - }

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    3.

    Which one is bidentate ligand?

    A

    C2O42βˆ’{{\rm{C}}_2}{\rm{O}}_4^{2 - }

    B

    NH2β‹…CH2β‹…CH2β‹…NH2{\rm{N}}{{\rm{H}}_2} \cdot {\rm{C}}{{\rm{H}}_2} \cdot {\rm{C}}{{\rm{H}}_2} \cdot {\rm{N}}{{\rm{H}}_2}

    C

    Both (1) and (2)

    D

    None of these

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    4.

    The compound having the lowest oxidation state of iron is

    A

    K4Fe(CN)6{{\rm{K}}_4}{\rm{Fe}}{\left( {{\rm{CN}}} \right)_6}

    B

    K2FeO4{{\rm{K}}_2}{\rm{Fe}}{{\rm{O}}_4}

    C

    Fe2O3{\rm{F}}{{\rm{e}}_2}{{\rm{O}}_3}

    D

    Fe(CO)5{\rm{Fe}}{\left( {{\rm{CO}}} \right)_5}

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    5.

    Which does not obey EAN rule?

    A

    [Cu(NH3)4]2+{\left[ {{\rm{Cu}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}} \right]^{2 + }}

    B

    [Zn(OH)4]2βˆ’{\left[ {{\rm{Zn}}{{\left( {{\rm{OH}}} \right)}_4}} \right]^{2 - }}

    C

    [HgI4]2βˆ’{\left[ {{\rm{Hg}}{{\rm{I}}_4}} \right]^{2 - }}

    D

    Fe(CO)5{\rm{Fe}}{\left( {{\rm{CO}}} \right)_5}

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    9.

    When EDTA solution is added to Mg2+M{g^{2 + }} ion solution, then which of the following statements is not true?

    A

    EDTA forms a 1:1 complex with Mg^{2+}.

    B

    The Mg-EDTA complex is stable.

    C

    EDTA does not form a complex with Mg^{2+}.

    D

    The formation of the Mg-EDTA complex reduces free Mg^{2+} ion concentration.

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    10.

    Point out the central ion ligand in the complex K2[Cd(CN)4]{{\rm{K}}_2}\left[ {{\rm{Cd}}{{\left( {{\rm{CN}}} \right)}_4}} \right]:

    A

    Cd+,β€…β€ŠCN1βˆ’{\rm{C}}{{\rm{d}}^ + },{\rm{\;C}}{{\rm{N}}^{1 - }}

    B

    Cd2+,β€…β€ŠCN1βˆ’{\rm{C}}{{\rm{d}}^{2 + }},{\rm{\;C}}{{\rm{N}}^{1 - }}

    C

    Cd2+,β€…β€ŠCN4βˆ’{\rm{C}}{{\rm{d}}^{2 + }},{\rm{\;C}}{{\rm{N}}^{4 - }}

    D

    Cd2+,β€…β€ŠCN2βˆ’{\rm{C}}{{\rm{d}}^{2 + }},{\rm{\;C}}{{\rm{N}}^{2 - }}

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