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    3.

    In the Hell-Volhard-Zelinsky reaction, carboxylic acids react with bromine in the presence of phosphorus. What is the major product formed when butanoic acid is treated with Br2Br_2 and P, followed by hydrolysis?

    A

    CH3CH2CH2COBrCH_3CH_2CH_2COBr

    B

    CH3CH2CHBrCOOHCH_3CH_2CHBrCOOH

    C

    CH3CH2CH2COOHCH_3CH_2CH_2COOH

    D

    CH3CH2CBr2COOHCH_3CH_2CBr_2COOH

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    9.

    In the following reaction C6H5CH2Brβ†’2)H3O+1) Mg, etherX{C_6}{H_5}C{H_2}Br\xrightarrow[{2){H_3}{O^ + }}]{{1)\,Mg,\,ether}}X. The product β€˜X’ is

    A

    C6H5 CH2O CH2C6H5{C_6}{H_5}\,C{H_2}O\,C{H_2}{C_6}{H_5}

    B

    C6H5 CH2OH{C_6}{H_5}\,C{H_2}OH

    C

    C6H5 CH3{C_6}{H_5}\,C{H_3}

    D

    C6H5CH2CH2C6H5{C_6}{H_5}C{H_2}C{H_2}{C_6}{H_5}

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    10.

    Which of the following reactions is most likely to proceed via a SN2S_N2 mechanism?

    A

    Reaction of tert-butyl bromide with aqueous sodium hydroxide

    B

    Reaction of 2-bromopropane with sodium methoxide in methanol

    C

    Reaction of methyl iodide with sodium cyanide in DMF

    D

    Reaction of 2-chloro-2-methylpropane with ethanol

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