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    2.

    Which of the following alkyl groups has the maximum +I + I effect

    A

    (CH3)2CHβˆ’{\left( {C{H_3}} \right)_2}CH{\rm{ }} -

    B

    (CH3)3Cβˆ’{\left( {C{H_3}} \right)_3}C -

    C

    CH3CH2βˆ’C{H_3}C{H_2} -

    D

    CH3βˆ’C{H_3} -

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    7.

    In hyper conjugation there is overlap between

    A

    Pβˆ’Ο€βˆ’orbitalsP - \pi - orbitals

    B

    2Ο€βˆ’orbitals2\pi - orbitals

    C

    dβˆ’andβ€‰Ο€βˆ’orbitalsd - and\,\pi - orbitals

    D

    Οƒβˆ’and pβˆ’orbitals\sigma - and\,p - orbitals

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    10.

    Which of the following order is correct regarding the acidity of carboxylic acids?

    A

    Cl3CCOOH>Cl2CHCOOH>ClCH2COOH{\rm{C}}{{\rm{l}}_3}{\rm{CCOOH}} > {\rm{C}}{{\rm{l}}_2}{\rm{CHCOOH}} > {\rm{ClC}}{{\rm{H}}_2}{\rm{COOH}}

    B

    Cl3CCOOH>Cl2CHCOOH<ClCH2COOH{\rm{C}}{{\rm{l}}_3}{\rm{CCOOH}} > {\rm{C}}{{\rm{l}}_2}{\rm{CHCOOH}} < {\rm{ClC}}{{\rm{H}}_2}{\rm{COOH}}

    C

    Cl3CCOOH⟨Cl2CHCOOH⟩ClCH2COOH{\rm{C}}{{\rm{l}}_3}{\rm{CCOOH}}\left\langle {{\rm{C}}{{\rm{l}}_2}{\rm{CHCOOH}}} \right\rangle {\rm{ClC}}{{\rm{H}}_2}{\rm{COOH}}

    D

    Cl3CCOOH<Cl2CHCOOH<ClCH2COOH{\rm{C}}{{\rm{l}}_3}{\rm{CCOOH}} < {\rm{C}}{{\rm{l}}_2}{\rm{CHCOOH}} < {\rm{ClC}}{{\rm{H}}_2}{\rm{COOH}}

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