1.

    A student attempts to purify a mixture of aniline and nitrobenzene by steam distillation. Which compound will distill over first, and why?

    A

    Nitrobenzene, due to its higher molecular weight

    B

    Aniline, due to its lower boiling point and formation of less extensive hydrogen bonds with water compared to nitrobenzene

    C

    Both will distill over simultaneously as they form an azeotropic mixture

    D

    Nitrobenzene, because it is less volatile than aniline

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    6.

    In sulphur detection of an organic compound, sodium nitroprusside solution is added to sodium extract. Formation of violet colour is due to

    A

    Na3Fe(CN)6{\rm{N}}{{\rm{a}}_3}{\rm{Fe}}{\left( {{\rm{CN}}} \right)_6}

    B

    Na3[Fe(CN)5NOS]{\rm{N}}{{\rm{a}}_3}\left[ {{\rm{Fe}}{{\left( {{\rm{CN}}} \right)}_5}{\rm{NOS}}} \right]

    C

    Fe(CNS)3{\rm{Fe}}{\left( {{\rm{CNS}}} \right)_3}

    D

    None of these

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