1.

    Which of the following carbocations is the most stable?

    A

    CH3CH2CH2CH2+CH_3CH_2CH_2CH_2^+

    B

    (CH3)3CH+(CH_3)_3CH^+

    C

    (CH3)3C+(CH_3)_3C^+

    D

    CH3CH2+CH_3CH_2^+

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    3.

    Which of the following statement is wrong?

    A

    Using Lassaigne’s test nitrogen and sulphur present in organic compound can be tested

    B

    Using Beilstein’s test the presence of halogen in a compound can be tested

    C

    In Lassaigne’s filtrate the nitrogen present in a organic compound is converted into NaCN

    D

    In the estimation of carbon, an organic compound is heated with CaO in a combustion tube

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    5.

    The order of stability of carbanions is :

    A

    CH3>1>2>3{\rm{CH}}_3^ - > {1^ \circ } > {2^ \circ } > {3^ \circ }

    B

    3>2>1>CH3{3^ \circ } > {2^ \circ } > {1^ \circ } > {\rm{CH}}_3^ -

    C

    3>1>2>CH3{3^ \circ } > {1^ \circ } > {2^ \circ } > {\rm{CH}}_3^ -

    D

    2>3>1>CH3{2^ \circ } > {3^ \circ } > {1^ \circ } > {\rm{CH}}_3^ -

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    8.

    Which of the following is the most stable carbocation

    A

    CH3C+H2C{H_3}\mathop C\limits^ + {H_2}

    B

    (CH3)2C+H{\left( {C{H_3}} \right)_2}\mathop C\limits^ + H

    C

    (CH3)3C+{\left( {C{H_3}} \right)_3}\mathop C\limits^ +

    D

    C6H5C+H2{C_6}{H_5}\mathop C\limits^ + {H_2}

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    9.

    Which of the following orders regarding relative stability of free radicals is correct?

    A

    3^ \circ <2^ \circ <1^ \circ

    B

    3^ \circ >2^ \circ >1^ \circ

    C

    1^ \circ <2^ \circ >3^ \circ

    D

    3^ \circ >2^ \circ <1^ \circ

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    10.

    The stability of a carbocation is increased by which of the following?

    A

    The presence of electron-withdrawing groups.

    B

    The absence of neighboring alkyl groups.

    C

    The presence of neighboring alkyl groups.

    D

    A negative charge on the carbon atom.

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