1.

    The observed freezing point depression of a 0.01 m aqueous solution of a weak acid HA is 0.0205 °C. If the KfK_f of water is 1.86 K kg/mol, which expression correctly calculates the percent ionization of the weak acid?

    A

    (0.0205/1.86/0.01)1(21)imes100 \frac{(0.0205/1.86/0.01) - 1}{(2-1)} imes 100

    B

    (1.86imes0.01/0.0205)1(21)imes100 \frac{(1.86 imes 0.01/0.0205) - 1}{(2-1)} imes 100

    C

    (0.0205/1.86/0.01)(21)imes100 \frac{(0.0205/1.86/0.01)}{(2-1)} imes 100

    D

    (1.86imes0.01imes0.0205)(21)imes100 \frac{(1.86 imes 0.01 imes 0.0205)}{(2-1)} imes 100

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    3.

    The order of osmotic pressure of isomolar solution of BaCl2,NaCl  and  sucroseBaC{l_2},NaCl\;and\;sucrose is

    A

    BaCl2>NaCl>sucroseBaC{l_2} > NaCl > sucrose

    B

    NaCl>BaCl2>sucroseNaCl > BaC{l_2} > {\rm{ }}sucrose

    C

    Sucrose>NaCl>BaCl2Sucrose > NaCl > BaC{l_2}

    D

    BaCl2>sucrose>NaClBaC{l_2} > sucrose > NaCl

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    10.

    Which of the following solutions will have highest boiling point

    A

    0.1  M  FeCl30.1{\rm{ }}\;M\;{\rm{FeC}}{{\rm{l}}_3}

    B

    0.1  M  BaCl20.1{\rm{ }}\;M\;{\rm{BaC}}{{\rm{l}}_2}

    C

    0.1  M  NaCl0.1{\rm{ }}\;M\;{\rm{NaCl}}

    D

    0.1  M  urea  NH2CONH20.1{\rm{ }}\;M\;urea\;{\rm{N}}{{\rm{H}}_2}{\rm{CON}}{{\rm{H}}_2}

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