1.

    When a substance is distributed between two immiscible solvents and remains in the same state in the solvent I, while, dissociates in the solvent II. If the concentration of solute are cI  and  cII{c_{\rm{I}}}\;{\rm{and}}\;{c_{{\rm{II}}}} in phase I and II respectively then :

    A

    cIcII(1α)=K\frac{{{c_{\rm{I}}}}}{{{c_{{\rm{II}}}}\left( {1 - {\rm{\alpha }}} \right)}} = K

    B

    cI(1α)cII=K\frac{{{c_{\rm{I}}}\left( {1 - {\rm{\alpha }}} \right)}}{{{c_{{\rm{II}}}}}} = K

    C

    cI(1β)cII=K\frac{{{c_{\rm{I}}}\left( {1 - {\rm{\beta }}} \right)}}{{{c_{{\rm{II}}}}}} = K

    D

    cIcII(1α)=K\frac{{{c_{\rm{I}}}}}{{\sqrt {{c_{{\rm{II}}}}\left( {1 - {\rm{\alpha }}} \right)} }} = K

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    6.

    A 0.001 molal solution of [Pt(NH3)4Cl4]\left[ {{\rm{Pt}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{C}}{{\rm{l}}_4}} \right] in water has a freezing point depression of 0.0054C0.0054^\circ C. If kf{k_f} for water is 1.80, the correct formulation of the above molecule is :

    A

    [Pt(NH3)4Cl3]Cl\left[ {{\rm{Pt}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{C}}{{\rm{l}}_3}} \right]{\rm{Cl}}

    B

    [Pt(NH3)4Cl2]Cl2\left[ {{\rm{Pt}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{C}}{{\rm{l}}_2}} \right]{\rm{C}}{{\rm{l}}_2}

    C

    [Pt(NH3)4Cl]Cl3\left[ {{\rm{Pt}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{Cl}}} \right]{\rm{C}}{{\rm{l}}_3}

    D

    [Pt(NH3)4Cl4]\left[ {{\rm{Pt}}{{\left( {{\rm{N}}{{\rm{H}}_3}} \right)}_4}{\rm{C}}{{\rm{l}}_4}} \right]

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    10.

    If a 5.25%  (wt./vol.)5.25\% {\rm{ }}\;\left( {wt./vol.} \right) solution of a non-electrolyte is isotonic with 1.50%  (wt./vol.)1.50\% {\rm{ }}\;\left( {wt./vol.} \right) solution of urea, (molwt=60)\left( {mol - wt{\rm{ }} = 60} \right) is the same solvent then the molecular weight of non-electrolyte is :

    A

    210.0  g    mol1210.0\;{\rm{g}}\;\;{\rm{mo}}{{\rm{l}}^{ - 1}}

    B

    90.0  g    mol190.0\;{\rm{g}}\;\;{\rm{mo}}{{\rm{l}}^{ - 1}}

    C

    115.0  g    mol1115.0\;{\rm{g}}\;\;{\rm{mo}}{{\rm{l}}^{ - 1}}

    D

    105  g    mol1105\;{\rm{g}}\;\;{\rm{mo}}{{\rm{l}}^{ - 1}}

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