1.

    A binary solution of two volatile liquids A and B deviates negatively from Raoult's Law. At a specific composition, the total vapor pressure is minimum. Which of the following statements is FALSE regarding this specific composition?

    A

    The vapor and liquid phases have identical compositions.

    B

    The boiling point is higher than that of either pure A or pure B.

    C

    The system deviates negatively from Raoult's Law.

    D

    The mole fraction of A in the vapor is always greater than that of B.

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    2.

    All form ideal solution except

    A

    C6H6andC6H5NH2{C_6}{H_6}\,\,and\,\,{C_6}{H_5}N{H_2}

    B

    C6H6andC6H5I{C_6}{H_6}\,\,and\,\,{C_6}{H_5}I

    C

    C6H5ClandC2H5Br{C_6}{H_5}Cl\,\,and\,\,{C_2}{H_5}Br

    D

    C6H5IandC6H5OH{C_6}{H_5}I\,\,and\,\,{C_6}{H_5}OH

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    3.

    PA{P_A} and PB{P_B} are the vapour pressures of pure liquid components AA and BB respectively of an ideal binary solution. If XA{X_A} represents the mole fraction of component AA , the total pressure of the solution will be

    A

    PA+XA(PBPA){P_A} + {X_A}\left( {{P_B} - {P_A}} \right)

    B

    PA+XA(PAPB){P_A} + {X_A}\left( {{P_A} - {P_B}} \right)

    C

    PB+XA(PBPA){P_B} + {X_A}\left( {{P_B} - {P_A}} \right)

    D

    PB+XA(PAPB){P_B} + {X_A}\left( {{P_A} - {P_B}} \right)

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    5.

    PA{P_A} and PB{P_B} are the vapour pressures of pure liquid components AA and BB respectively of an ideal binary solution. If XA{X_A} represents the mole fraction of component AA , the total pressure of the solution will be

    A

    PA+XA(PBPA){P_A} + {X_A}\left( {{P_B} - {P_A}} \right)

    B

    PA+XA(PAPB){P_A} + {X_A}\left( {{P_A} - {P_B}} \right)

    C

    PB+XA(PBPA){P_B} + {X_A}\left( {{P_B} - {P_A}} \right)

    D

    PB+XA(PAPB){P_B} + {X_A}\left( {{P_A} - {P_B}} \right)

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    6.

    Which of the following is the expression of Raoult’s law?

    (p={p = } vapour pressure of pure solvent, ps{{p_s}} =vapour pressure of the solution)

    A

    ppsp=nn+N\frac{{p - {p_s}}}{p} = \frac{n}{{n + N}}

    B

    pspp=NN+n\frac{{{p_s} - p}}{p} = \frac{N}{{N + n}}

    C

    ppsps=NNn\frac{{p - {p_s}}}{{{p_s}}} = \frac{N}{{N - n}}

    D

    pspps=NnN\frac{{{p_s} - p}}{{{p_s}}} = \frac{{N - n}}{N}

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    10.

    For dilute solution Raoult’s law states that

    A

    The relative lowering of vapour pressure is equal to mole fraction of solute

    B

    The lowering of vapour pressure is equal to the mole fraction of solute

    C

    The vapour pressure of the solution is equal to mole fraction of the solvent

    D

    The relative lowering of vapour pressure is proportional to amount of solute in solution

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