1.

    Which statement BEST describes the relationship between Raoult's and Henry's Laws?

    A

    Henry's Law is applicable for all solutions, while Raoult's Law is only for ideal solutions.

    B

    Raoult's Law is a special case of Henry's Law where the Henry's law constant equals the vapor pressure of the pure component.

    C

    Henry's Law describes the behavior of the solute in a dilute solution, while Raoult's Law describes the behavior of the solvent.

    D

    Both laws are only applicable to solutions of non-volatile solutes.

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    2.

    Positive deviation is observed in case of

    A

    HNO3+H2OHN{O_3} + {H_2}O

    B

    CHCl3+(C2H5)2OCHC{l_3} + {\left( {{C_2}{H_5}} \right)_2}O

    C

    CH3COCH3+C6H5NH2C{H_3}COC{H_3} + {C_6}{H_5}N{H_2}

    D

    C6H6+CH3COCH3{C_6}{H_6} + C{H_3}COC{H_3}

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    6.

    PA{P_A} and PB{P_B} are the vapour pressures of pure liquid components AA and BB respectively of an ideal binary solution. If XA{X_A} represents the mole fraction of component AA , the total pressure of the solution will be

    A

    PA+XA(PBβˆ’PA){P_A} + {X_A}\left( {{P_B} - {P_A}} \right)

    B

    PA+XA(PAβˆ’PB){P_A} + {X_A}\left( {{P_A} - {P_B}} \right)

    C

    PB+XA(PBβˆ’PA){P_B} + {X_A}\left( {{P_B} - {P_A}} \right)

    D

    PB+XA(PAβˆ’PB){P_B} + {X_A}\left( {{P_A} - {P_B}} \right)

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    10.

    For an ideal solution of benzene and toluene, which of the following is true?

    A

    Ξ”Hmix>0\Delta H_{mix} > 0 and Ξ”Vmix>0\Delta V_{mix} > 0

    B

    Ξ”Hmix=0\Delta H_{mix} = 0 and Ξ”Vmix=0\Delta V_{mix} = 0

    C

    Ξ”Hmix<0\Delta H_{mix} < 0 and Ξ”Vmix<0\Delta V_{mix} < 0

    D

    Ξ”Hmix>0\Delta H_{mix} > 0 and Ξ”Vmix<0\Delta V_{mix} < 0

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