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A system at equilibrium consisting of , and in a sealed vessel at constant temperature is subjected to a sudden increase in pressure. According to Le Chatelier's principle, which of the following is most likely to occur?
The equilibrium shifts towards the reactants.
The equilibrium shifts towards the product.
No significant shift in equilibrium occurs.
The concentration of NO increases significantly.
The solubility product () of in water at 25Β°C is . A solution of in water is in equilibrium with solid . If a small amount of is added to this saturated solution, what will happen to the solubility () and of ?
increases, increases
decreases, remains constant
remains constant, decreases
increases, remains constant
Consider the endothermic reaction: . A sealed container filled with an equilibrium mixture of and is suddenly immersed in an ice bath. Which of the following changes will occur initially?
The concentration of increases.
The concentration of increases.
The equilibrium constant () increases.
No change occurs.
In the Haber-Bosch process for ammonia synthesis, , the reaction is exothermic. To maximize ammonia yield at high pressure, which catalyst would theoretically be most effective, assuming all are equally active at standard conditions?
A catalyst that equally adsorbs all reactants and products.
A catalyst that selectively adsorbs .
A catalyst that selectively adsorbs and but not .
The choice of catalyst does not affect the equilibrium yield.
A reaction has a of 0.1 at 298 K. If initially 1 mole each of A and B are introduced into a 1L vessel, and the system is allowed to reach equilibrium, what approximate pressure change () must be applied to double the equilibrium concentration of C?
-0.17RT
+0.08RT
-0.34RT
+0.17RT
A reaction mixture for the reversible reaction is at equilibrium at a given temperature. If the equilibrium partial pressures are = 0.2 atm, = 0.4 atm, and = 0.6 atm, what would be the effect of increasing the pressure of A to 0.3 atm while keeping the volume and temperature constant?
The partial pressure of B will decrease and the partial pressure of C will increase.
The partial pressure of B will increase and the partial pressure of C will decrease.
The partial pressures of B and C will both increase.
The partial pressures of B and C will remain unchanged.
For the reaction , = -198 kJ/mol. Which of the following changes will NOT increase the yield of at equilibrium?
Increasing the temperature
Increasing the pressure
Adding a catalyst
Removing some
For the reversible reaction at a certain temperature, the partial pressures at equilibrium are atm, atm, and atm. If the total pressure is suddenly doubled by adding an inert gas at constant volume, the new partial pressure of at the newly established equilibrium will be closest to:
0.4 atm
0.8 atm
1.6 atm
0.6 atm
Which factor does NOT affect the equilibrium position of a reversible reaction?
Temperature
Pressure
Concentration of reactants
Catalyst
For the reaction at equilibrium, increasing the pressure by decreasing the volume of the container will:
Shift the equilibrium towards the formation of ammonia.
Shift the equilibrium towards the formation of nitrogen and hydrogen.
Have no effect on the equilibrium position.
Increase the value of the equilibrium constant.