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For a reaction A + B β C, the rate law is found to be Rate = k[A]Β²[B]β»ΒΉ. If the concentration of A is tripled while keeping the concentration of B constant, the factor by which the reaction rate changes is:
3
1/3
1/9
9
For a zero-order reaction, the plot of concentration of reactant versus time is:
a straight line with a positive slope
a straight line with a negative slope
an exponential decay curve
a hyperbolic curve
The half-life of a first-order reaction is 20 minutes. What fraction of the reactant remains after 80 minutes?
1/2
1/4
1/8
1/16
A reaction between gases X and Y follows the rate law: Rate = k[X]Β²[Y]. If the concentration of X is tripled and the concentration of Y is halved, the new rate will be:
1.5 times the original rate
4.5 times the original rate
9 times the original rate
0.75 times the original rate
Two molecules A and B collide, but no reaction occurs. Which of the following MUST be true?
The molecules did not collide with the correct orientation.
The molecules are not reactive under any conditions.
The collision did not have sufficient energy to overcome the activation energy barrier.
The temperature of the system is too low for any reaction to occur.
The pre-exponential factor (A) in the Arrhenius equation is related to the:
Activation energy of the reaction
Enthalpy change of the reaction
Frequency of collisions with proper orientation
Temperature of the reaction
The hydrolysis of tert-butyl bromide in an aqueous medium follows the mechanism. If the concentration of tert-butyl bromide is doubled, and the concentration of water is tripled, how will the rate of the reaction be affected?
Doubles
Triples
Increases six-fold
Remains unchanged
A reaction follows the rate law: Rate = . If the concentrations of both A and B are halved, the rate of the reaction will become:
1/2 times the original rate
1/4 times the original rate
1/(4β2) times the original rate
1/8 times the original rate