Which of the following deviations from Raoult's law is associated with the formation of a maximum boiling azeotrope?
Negative deviation
Positive deviation
No deviation
Both positive and negative deviations
Related Questions
An aqueous solution is 1.0 molal in KI. Which change will cause the vapour pressure of solution to increase :
Addition of NaCl
Addition of
Addition of 1.0 molal KI
Addition of water
For dilute solution Raoultโs law states that
The relative lowering of vapour pressure is equal to mole fraction of solute
The lowering of vapour pressure is equal to the mole fraction of solute
The vapour pressure of the solution is equal to mole fraction of the solvent
The relative lowering of vapour pressure is proportional to amount of solute in solution
Benzene and toluene form nearly ideal solutions. At , the vapour pressure of benzene is 75 torr and that of toluene is 22 torr. The partial vapour pressure of benzene at for a solution containing 78 g of benzene and 46 g of toluene in torr is
53.5
37.5
25
50
A solution containing components and follows Raoultโs law
attraction force is greater than and
attraction force is less than and
attraction force remains same as and
Volume of solution is different from sum of volume of solute and solvent
An aqueous solution of methanol in water has vapour pressure
Less than that of water
More than that of water
Equal to that of water
Equal to that of methanol
The relative lowering of vapour pressure produced by dissolving 71.5 g of a substance in 1000 g of water is 0.00713. The molecular weight of the substance will be :
180
18
342
60
For a mixture of two liquids to behave ideally, the interactions between unlike molecules should be:
Stronger than the interactions between like molecules
Weaker than the interactions between like molecules
Equal to the interactions between like molecules
Negligible compared to the interactions between like molecules
At , the vapour pressure of pure liquid 'A'is 520 mm Hg and that of pure liquid 'B' is 1000 mm Hg. If a mixture of solution 'A'\;{\rm{and}}\;'B' boils at and 1 atm pressure, the amount of 'A' in the mixture is : (1 atm = 760 mm Hg)
50 mol per cent
52 mol per cent
34 mol per cent
48 mol per cent
A binary solution of two volatile liquids A and B deviates negatively from Raoult's Law. At a specific composition, the total vapor pressure is minimum. Which of the following statements is FALSE regarding this specific composition?
The vapor and liquid phases have identical compositions.
The boiling point is higher than that of either pure A or pure B.
The system deviates negatively from Raoult's Law.
The mole fraction of A in the vapor is always greater than that of B.
For an ideal binary liquid solution with which relation between (mole fraction of A in liquid phase) and (mole fraction of A in vapour phase) is correct, and are mole fraction of B in liquid and vapour phase respectively :
cannot be corelated