Two liquids A and B form an ideal solution. At a certain temperature, the vapor pressure of pure A is 400 mm Hg and that of pure B is 700 mm Hg. If the mole fraction of A in the liquid phase is 0.4, what is the mole fraction of A in the vapor phase?
0.276
0.571
0.724
0.420
Related Questions
When an ideal binary solution is in equilibrium with its vapour, molar ratio of the two components in the solution and in the vapour phase is :
Same
Different
May or may not be same depending upon volatile nature of the two components
None of the above
Two liquids X and Y form an ideal solution. The mixture has a vapour pressure of 400 mm at 300 K when mixed in the molar ratio of 1:1 and a vapour pressure of 350 mm when mixed in the molar ratio of 1:2 at the same temperature. The vapour pressures of the two pure liquids X and Y respectively are
250 mm, 550 mm
350 mm, 450 mm
350 mm, 700 mm
550 mm, 250 mm
For an ideal binary liquid solution with which relation between (mole fraction of A in liquid phase) and (mole fraction of A in vapour phase) is correct, and are mole fraction of B in liquid and vapour phase respectively :
cannot be corelated
One component of a solution follows Raoultβs law over the entire range . The second component must follow Raoultβs law in the range when is
Close to zero
Close to 1
At 25Β°C, an equimolar mixture of benzene (vapor pressure = 12.8 kPa) and toluene (vapor pressure = 3.85 kPa) forms an ideal solution. If the total pressure above the solution is 8.325 kPa, which component has a higher partial pressure in the vapor phase?
Benzene
Toluene
Both have equal partial pressures.
Cannot be determined.
When the vapour pressure of solutions of two liquids are less than those expected from ideal solutions, they are said to show :
Positive deviations from ideal behaviour
Negative deviations from ideal behaviour
Positive deviations for lower concentrations and negative deviations for higher concentration
None of the above
The plots of (where are the mole fraction of liquid A in liquid and vapour phase respectively) is linear with slope and intercepts respectively:
Slope = and Intercept =
Slope = and Intercept =
Slope = and Intercept =
Slope = and Intercept =
Which of the following deviations from Raoult's law is associated with the formation of a maximum boiling azeotrope?
Negative deviation
Positive deviation
No deviation
Both positive and negative deviations
At 25Β°C, the vapor pressures of pure benzene and toluene are 12.8 kPa and 3.85 kPa, respectively. If an ideal solution is prepared with 2 moles of benzene and 1 mole of toluene, what is the total vapor pressure above the solution?
6.43 kPa
9.78 kPa
16.65 kPa
8.33 kPa
Which of the following mixture does not show positive deviation from the Raoultβs law?
Benzene + acetone
Acetone + ethanol
Acetone + chloroform
Water + ethanol