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Raising the temperature of a reversible chemical reaction :
Favours the forward rate only
Favours the backward rate only
Favours both the forward and backward rates as the case may be
Favours neither the forward nor backward rates
The activation energies of two reactions are . If the temperature of the system is increased from , the rate constant of the reactions changes from in the first reaction and in the second reaction. Predict which of the following expression is correct?
\frac{k_2'}{k_1'} > \frac{k_2''}{k_1''}
\frac{k_2'}{k_1'} < \frac{k_2''}{k_1''}
\frac{k_2'}{k_1'} = \frac{k_2''}{k_1''}
\frac{k_2'}{k_1'} \leq \frac{k_2''}{k_1''}
The half life for a reaction β¦ of temperature.
Independent
Increased with increase
Decreased with increase
Dependent
The rate constant of a reaction at temperature is 10 times less than the rate constant at . What is the activation energy ( ) of the reaction?
The rate constant of a reaction at temperature is 10 times less than the rate constant at . What is the activation energy ( ) of the reaction?
Arrhenius equation may not be represented as
k = A * e^(-Ea/RT)
ln k = ln A - Ea/RT
ln(k2/k1) = Ea/R * (1/T1 - 1/T2)
k = A * e^(Ea/RT)
The activation energy of a reaction is . The increase in the rate constant when its temperature is raised from is approximately
10%
15%
29%
50%
Activation energy of a reaction
Measure the rate constant at a single temperature.
Determine the slope of the ln(k) vs 1/T plot and multiply it by -R.
Calculate the average rate of the reaction at different temperatures.
Measure the equilibrium constant of the reaction.
The velocity constant of a reaction at was found to be , it will be
6.4 x 10^-3
3.2 x 10^-2
1.6 x 10^-3
1.28 x 10^-2
The reason for almost doubling the rate of reaction on increasing the temperature of the reaction system by is
The value of threshold energy increases
Collision frequency increases
The fraction of the molecules having energy equal to threshold energy increases
Activation energy decreases