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In the molecule, the central nitrogen atom can have different formal charges depending on the Lewis structure. Which of the following formal charge distributions (N-N-O) is the LEAST likely to contribute to the resonance hybrid?
0, +1, -1
+1, 0, -1
+2, 0, -2
+1, -1, 0
Considering the isoelectronic series S2-, Cl-, Ar, K+, Ca2+, and the fact that electron-electron repulsion in the outermost shell influences effective nuclear charge and hence atomic radius, which of the following statements is INCORRECT?
The radius decreases from S2- to Ca2+.
Ca2+ has the smallest radius in the series.
Electron-electron repulsion is the dominant factor influencing the radius in this series, causing the radius to increase from S2- to Ca2+.
All species have the same number of electrons but different numbers of protons.
Which of the following correctly explains the observed trend in atomic radii down Group 13 (Boron Family) considering the influence of d- and f-block electron filling in subsequent periods?
Atomic radii consistently increase from B to Tl due to the increasing number of electron shells.
Ga has a significantly smaller radius than Al due to the lanthanide contraction.
Tl has a larger radius than In, but the increase is smaller than expected due to the d-block contraction.
While the general trend is an increase in radius down the group, Ga experiences a smaller than expected increase in radius compared to Al due to the poor shielding effect of the 3d electrons, while Tl exhibits a smaller than expected increase compared to In due to the poor shielding of both the 4f and 5d electrons.
The reaction of 1 equivalent of with 1-phenylpropyne in the presence of peroxides yields predominantly:
1-Bromo-1-phenylpropene
2-Bromo-1-phenylpropene
1-Bromo-1-phenylpropane
2-Bromo-1-phenylpropane
Which alkyne, upon reaction with sodamide () followed by treatment with 1-bromopropane, would yield 4-methylhex-2-yne?
but-1-yne
3-methylbut-1-yne
pent-1-yne
3,3-dimethylbut-1-yne
How many isomers, including stereoisomers, are possible for the compound with the molecular formula ?
2
3
4
5
Which of the following high-spin complexes exhibits the largest Jahn-Teller distortion?
[Cr(HO)]
[Cr(HO)]
[Mn(HO)]
[Fe(HO)]
An unknown ether, upon treatment with HI, produces a single alkyl iodide. This alkyl iodide, when reacted with sodium in dry ether, forms n-hexane. Identify the original ether.
Diethyl ether
Dipropyl ether
Dibutyl ether
Diisopropyl ether